Article 13 – Electro-Chemo-Mechanical Coupling in Hf0.5Zr0.5O2 Ferroionic Heterostructures

Abstract: The development of smart materials that can react to external stimuli and provide controlled and frequently reversible responses is facilitated by the coupling of physical effects. In this work, a photo-pyroelectric effect based on a piezoelectric polyvinylidene fluoride-trifluoroethylene (P(VDF-TrFE)) polymer composite with fullerene C60 incorporated at different concentrations (1, 3,

Abstract: Study of nanoscale hafnia-zirconia physical properties is the key topic in fundamental and applied science. However, charge transport mechanisms and magnetic properties of HfxZr1-xO2 nanoparticles are very poorly studied both theoretically and experimentally. In this work we observed a superparamagnetic-like and superparaelectric-like response of ultra-small HfxZr1-xO2-y nanoparticles prepared by the solid-state

Abstract: Ferroelectricity in Hf0.5Zr0.5O2 (HZO) originates from a polymorphic landscape where the metastable orthorhombic phase competes with monoclinic and tetragonal forms, making functional properties highly sensitive to structural instability. Recent strategies have exploited ionic-vacancy mechanisms, either through redox interactions with the environment or by employing ferroionic heterostructures, to enhance ferroelectric performance.

Abstract: The contribution of flexoelectric coupling to the long-range order parameter fluctuations in ferroics can be critically important to the ferron dispersion and related polar, pyroelectric, and electrocaloric (EC) properties. Here, we calculate analytically the dispersion relations of soft optic and acoustic flexocoupling-induced phonons and ferrons by incorporating the flexoelectric

Abstract: Peptide nanotubes (PNTs) are bioelectrets that exhibit piezoelectricity, pyroelectricity, ferroelectricity, and birefringence. Birefringence is an optical property that can be used to determine the degree of order, orientation, size, and shape of PNTs. In this work, a custom-built optical apparatus is used to quantitatively measure birefringence in three dimensions

Abstract: Natural organic piezoelectric materials have been the subject of intense research over the last couple of decades. This interest is due to their remarkable piezoelectric characteristics, biocompatibility, biodegradability, outstanding mechanical properties, and cost-effective fabrication processes. This chapter presents an extensive overview about the recent advances in natural organic piezoelectric